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Chapter 8:Hazard Analysis—Lava and VOG <br /> toxic at excessive levels of consumption. Recent surveys of domestic catchment <br /> systems in the area of HOVE and Volcano have shown that plume constituents are <br /> contributing chloride, sulfate and fluoride ions to catchment waters. HOVE water <br /> samples showed the higher concentrations of these ions, by factors of four to ten <br /> above those of Volcano, and reflect a higher integrated exposure to plume deposition <br /> than did the Volcano community. (The higher rainfall rates and flow through the <br /> catchment systems in Volcano is also likely to contribute to the lower values there.) <br /> The median values of all ions for both communities were considerably lower than <br /> drinking water standards but some samples from both the HOVE and Volcano areas <br /> did show values that were substantially higher than the median values and were much <br /> closer to drinking water limits. Hence, significant changes in the plume discharge <br /> rates or in weather patterns could warrant further monitoring of the catchment <br /> systems. <br /> Of potentially greater concern is the deposition of fluoride salts onto forage crops. <br /> The scientific literature has documented a number of events where sheep, cattle, and <br /> horses have suffered significant losses as a result of both acute exposure as well as <br /> chronic exposure and accumulation of fluoride salts by grazing animals. Although <br /> there have been a few anecdotal reports of symptoms of fluorosis by some ranchers <br /> on the Big Island, further investigations will be necessary to determine whether the <br /> forage crops are accumulating sufficient fluoride to be of concern in the downwind <br /> communities. <br /> 8.1.2.1.2 TEB Vent and Pu'u O'o <br /> The TEB vent, located on the Kilauea East Rift Zone (KERZ), is discharging gases similar to <br /> those at Halema'uma'u, albeit at different relative concentrations. Due to the dynamics of gas <br /> release from magma, the relative amount of carbon dioxide to sulfur dioxide is lower at the <br /> TEB vent than at Halema'uma'u and the concentrations of HCl and HF are somewhat higher. <br /> This discharge is also likely to have lower amounts of sulfur trioxide and hydrogen sulfide <br /> than the summit discharge. The sulfur dioxide emission rates from TEB Vent have ranged as <br /> high as 2000 tonnes per day but currently are in the range of 1000 tonnes per day or <br /> somewhat less. <br /> The chemical processes occurring in the TEB plume, are in most respects, identical to those <br /> occurring in the Halema'uma'u plume but, because of the vent's location on the KERZ, the <br /> trajectory taken by the plume (during normal trade wind conditions) is substantially different <br /> from that of the former. Whereas the Halema'uma'u plume is often affected by the upslope <br /> winds generated by daytime heating of Mauna Loa's flanks, the TEB plume is far enough <br /> off-shore that it only rarely affects the south-east flank of Mauna Loa. However, the TEB <br /> plume has shown a history of becoming trapped in the eddy system on the southwest and <br /> western flank of Mauna Loa and has consistently affected air quality on the Kona side of the <br /> island since the initiation of the Pu'u O'o eruption in 1983. With the onset of the <br /> Halema'uma'u eruption, the addition of its plume to that of TEB has produced further <br /> deterioration in the Kona air quality. <br /> 8-7 Hawaii County Multi-Hazard Mitigation Plan <br />