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2.0 EVALUATION OF LANDFILL SUBSURFACE CONDITIONS <br />2.1 BACKGROUND <br />Post -operations air emissions from the Kailua Kona Landfill have <br />reportedly included low levels of VOCs, including benzene, toluene, <br />ethylbenzene, carbon monoxide (CO), and hydrogen sulfide (H2S) <br />(ATSDR,1994). Other constituents monitored in the emissions from the <br />site include 02, CO2, and CH4, basic atmospheric gases that are tracked to <br />determine possible subsurface fires. However, an active landfill gas <br />management system is not currently operational at the site. Therefore, an <br />analysis of the current condition of the landfill from a physical and <br />chemical perspective is required to assess the nature and extent of landfill <br />emissions, and the potential for subsurface fires within the waste mound. <br />The investigation and monitoring activities should include both existing <br />gas monitoring probes and extraction wells, as well as supplemental, <br />focused subsurface explorations. Critical to this assessment is knowledge <br />of the east -center, north -center and northwest portions of the landfill, <br />which have been identified most recently as areas of concern. <br />Several techniques for subsurface fire suppression have been attempted at <br />the landfill. Smothering the fires, involving eliminating the supply of 02 <br />to the fire source either via soil cover and compaction, cover and leakage <br />repair, and/or the injection of a suppressing gas, such as CO2, has been <br />attempted. None of these previous efforts were performed to an extent or <br />duration necessary to substantially suppress subsurface fires. Excavating <br />the cover material within the landfill waste and flooding burning material <br />with water and/or suppressants such as a fire -retardant foam is a method <br />that has been attempted at other landfill sites with mixed results (TriData, <br />2002). A version of removing the cover material and burning waste <br />material from a known hot zone, and extinguishing by way of foam <br />flooding is proposed for the Kailua-Kona Landfill to suppress ongoing <br />subsurface fires. <br />If the fire is extensive and temperatures are high, applied water may <br />convert to steam upon contact with the burning waste material, and may <br />limit fire -suppression effectiveness. Large volumes of suppression water <br />could potentially infiltrate to the underlying groundwater aquifer, <br />potentially impacting groundwater quality by leaching contaminants from <br />waste materials. Use of a foam suppression material is less likely to result <br />in contaminant leaching and is believed to be a more environmentally -safe <br />suppression technique. <br />ERM 5 KAILUA-KONA LANDFILL/ 0061204 - 3/14/2008 <br />